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Direct conversion of chemical energy → electrical via redox at separate electrodes; continuous operation if fuel/oxidant supplied.
H₂–O₂ (acidic) cell: Anode: H₂ → 2H⁺ + 2e⁻ , Cathode: ½O₂ + 2H⁺ + 2e⁻ → H₂O , Overall: H₂ + ½O₂ → H₂O + energy
Material that slows fast neutrons → thermal neutrons to enhance fission probability. Examples: light water, heavy water (D₂O), graphite, Be.
Minimum mass of fissile material needed to sustain a self-maintaining chain reaction. Depends on density, geometry, purity, and neutron reflectors.
Rechargeable battery: PbO₂ (pos), Pb (neg), electrolyte H₂SO₄.
Discharge: PbO₂ + Pb + 2H₂SO₄ → 2PbSO₄ + 2H₂O (≈2.0 V per cell).
Charge: Reverse of the above reaction.
Due to mass defect and rise in binding energy per nucleon; tiny Δm converts to energy by E = mc².
Reduces neutron energy to thermal range → increases fission cross-section of U-235/Pu-239, stabilizing the chain reaction; should have low absorption cross-section.
Fission: ¹²³⁵U + ¹n → ¹⁴¹Ba + ⁹²Kr + 3 ¹n + energy
Fusion: ²H + ³H → ⁴He + ¹n + energy
Bacteria at the anode oxidize organics → release e⁻/H⁺; e⁻ travel through circuit, H⁺ through membrane; at cathode typically O₂ is reduced to H₂O. Generates power from wastewater/biomass.
| Feature | Primary | Secondary |
|---|---|---|
| Reusability | Single-use | Rechargeable |
| Reaction | Irreversible | Reversible |
| Examples | Dry cell, Alkaline | Lead–acid, Li-ion, Ni-MH |
PN-junction device converting light → electricity (photovoltaic effect).
Current equation: I = Iph − I₀\{e^{qV/kT} − 1\}; efficiency η = Pout/Pin.
²³⁵U + ¹n → ²³⁶U* → ¹⁴¹Ba + ⁹²Kr + 3 ¹n + energy (many product pairs possible; ²³⁶U* is excited intermediate).
Wind turns rotor blades → shaft → generator; power captured scales as P ∝ ½ρ A v³ (air density ρ, swept area A, wind speed v).
Reactor using fast neutrons that produces more fissile fuel than it consumes (breeding ratio > 1). Example pathway: ²³⁸U(n,γ) → ²³⁹U → ²³⁹Np → ²³⁹Pu.
Ensures neutrons reach thermal energies without being absorbed; chosen for high scattering and low absorption cross-sections (e.g., D₂O, graphite).
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